Operando characterization and regulation of metal dissolution and redeposition dynamics near battery electrode surface

Thackeray, M. M. & Amine, K. LiMn₂O₄ spinel and substituted cathodes. Nat. Energy 6, 566 (2021).

Article  CAS  Google Scholar 

Kim, D. K. et al. Spinel LiMn₂O₄ nanorods as lithium ion battery cathodes. Nano Lett. 8, 3948–3952 (2008).

Article  CAS  Google Scholar 

Xia, H., Luo, Z. & Xie, J. Nanostructured LiMn₂O₄ and their composites as high-performance cathodes for lithium-ion batteries. Prog. Nat. Sci.: Mater. Int. 22, 572–584 (2012).

Article  Google Scholar 

Lun, Z. et al. Design principles for high-capacity Mn-based cation-disordered rocksalt cathodes. Chem 6, 153–168 (2020).

Article  CAS  Google Scholar 

Li, H. et al. Toward high-energy Mn-based disordered-rocksalt Li-ion cathodes. Joule 6, 53–91 (2022).

Article  Google Scholar 

Zhang, Y. et al. Investigating particle size‐dependent redox kinetics and charge distribution in disordered rocksalt cathodes. Adv. Funct. Mater. 32, 2110502 (2022).

Article  CAS  Google Scholar 

Sun, X., Xiao, R., Yu, X. & Li, H. First-principles simulations for the surface evolution and Mn dissolution in the fully delithiated spinel LiMn₂O₄. Langmuir 37, 5252–5259 (2021).

Article  CAS  Google Scholar 

Zhan, C., Wu, T., Lu, J. & Amine, K. Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes—a critical review. Energy Environ. Sci. 11, 243–257 (2018).

Article  CAS  Google Scholar 

Tang, D. et al. Surface structure evolution of LiMn₂O₄ cathode material upon charge/discharge. Chem. Mater. 26, 3535–3543 (2014).

Article  CAS  Google Scholar 

Zhou, G. et al. Mn ion dissolution mechanism for lithium-ion battery with LiMn₂O₄ cathode: in situ ultraviolet–visible spectroscopy and ab initio molecular dynamics simulations. J. Phys. Chem. Lett. 11, 3051–3057 (2020).

Article  CAS  Google Scholar 

Zhu, X. et al. LiMnO₂ cathode stabilized by interfacial orbital ordering for sustainable lithium-ion batteries. Nat. Sustain. 4, 392–401 (2021).

Article  Google Scholar 

Lin, R. et al. Characterization of the structure and chemistry of the solid–electrolyte interface by cryo-EM leads to high-performance solid-state Li-metal batteries. Nat. Nanotechnol. 17, 768–776 (2022).

Article  CAS  Google Scholar 

Cao, L. et al. Fluorinated interphase enables reversible aqueous zinc battery chemistries. Nat. Nanotechnol. 16, 902–910 (2021).

Article  CAS  Google Scholar 

Liu, T. et al. In situ quantification of interphasial chemistry in Li-ion battery. Nat. Nanotechnol. 14, 50–56 (2019).

Article  CAS  Google Scholar 

Xiang, Y. et al. Quantitatively analyzing the failure processes of rechargeable Li metal batteries. Sci. Adv. 7, eabj3423 (2021).

Article  CAS  Google Scholar 

Liu, T. et al. Correlation between manganese dissolution and dynamic phase stability in spinel-based lithium-ion battery. Nat. Commun. 10, 4721 (2019).

Article  Google Scholar 

Xu, C. et al. Bulk fatigue induced by surface reconstruction in layered Ni-rich cathodes for Li-ion batteries. Nat. Mater. 20, 84–92 (2021).

Article  CAS  Google Scholar 

Lin, F. et al. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries. Nat. Commun. 5, 3529 (2014).

Article  Google Scholar 

Liu, X. et al. Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy. Nat. Commun. 4, 2568 (2013).

Article  Google Scholar 

Yuan, Y., Amine, K., Lu, J. & Shahbazian-Yassar, R. Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy. Nat. Commun. 8, 15806 (2017).

Article  CAS  Google Scholar 

Jaumaux, P. et al. Localized water‐in‐salt electrolyte for aqueous lithium‐ion batteries. Angew. Chem. Int. Ed. 60, 19965–19973 (2021).

Article  CAS  Google Scholar 

Suo, L. et al. ‘Water-in-salt’ electrolyte enables high-voltage aqueous lithium-ion chemistries. Science 350, 938–943 (2015).

Article  CAS  Google Scholar 

Xu, J. et al. Aqueous electrolyte design for super-stable 2.5 V LiMn₂O₄ || Li₄Ti₅O₁₂ pouch cells. Nat. Energy 7, 186–193 (2022).

Article  CAS  Google Scholar 

Xie, J., Liang, Z. & Lu, Y.-C. Molecular crowding electrolytes for high-voltage aqueous batteries. Nat. Mater. 19, 1006–1011 (2020).

Article  CAS  Google Scholar 

Wang, C. et al. Overlooked electrolyte destabilization by manganese (ii) in lithium-ion batteries. Nat. Commun. 10, 3423 (2019).

Article  Google Scholar 

Leifer, N. et al. Studies of spinel-to-layered structural transformations in LiMn₂O₄ electrodes charged to high voltages. J. Phys. Chem. C 121, 9120–9130 (2017).

Article  CAS  Google Scholar 

Vissers, D. R. et al. Role of manganese deposition on graphite in the capacity fading of lithium ion batteries. ACS Appl. Mater. Interfaces 8, 14244–14251 (2016).

Article  CAS  Google Scholar 

Ren, Q., Yuan, Y. & Wang, S. Interfacial strategies for suppression of Mn dissolution in rechargeable battery cathode materials. ACS Appl. Mater. Interfaces 14, 23022–23032 (2021).

Xu, W. et al. Understanding the effect of Al doping on the electrochemical performance improvement of the LiMn₂O₄ cathode material. ACS Appl. Mater. Interfaces 13, 45446–45454 (2021).

Article  CAS  Google Scholar 

Lee, S., Cho, Y., Song, H., Lee, K. T. & Cho, J. Carbon‐coated single‐crystal LiMn₂O₄ nanoparticle clusters as cathode material for high‐energy and high‐power lithium‐ion batteries. Angew. Chem. Int. Ed. 51, 8748–8752 (2012).

Article  CAS  Google Scholar 

Wandt, J. et al. Transition metal dissolution and deposition in Li-ion batteries investigated by operando X-ray absorption spectroscopy. J. Mater. Chem. A 4, 18300–18305 (2016).

Article  CAS  Google Scholar 

Gao, X. et al. Oxygen loss and surface degradation during electrochemical cycling of lithium-ion battery cathode material LiMn₂O₄. J. Mater. Chem. A 7, 8845–8854 (2019).

Article  CAS  Google Scholar 

Santo, K. P. & Neimark, A. V. Effects of metal-polymer complexation on structure and transport properties of metal-substituted polyelectrolyte membranes. J. Colloid Interface Sci. 602, 654–668 (2021).

Article  CAS  Google Scholar 

Kumar, R., Pasupathi, S., Pollet, B. G. & Scott, K. Nafion-stabilised platinum nanoparticles supported on titanium nitride: an efficient and durable electrocatalyst for phosphoric acid based polymer electrolyte fuel cells. Electrochim. Acta 109, 365–369 (2013).

Article  CAS  Google Scholar 

Kuai, C. et al. Phase segregation reversibility in mixed-metal hydroxide water oxidation catalysts. Nat. Catal. 3, 743–753 (2020).

Article  CAS  Google Scholar 

Yang, Y. et al. Quantification of heterogeneous degradation in Li‐ion batteries. Adv. Energy Mater. 9, 1900674 (2019).

Article  Google Scholar 

Li, J. et al. Dynamics of particle network in composite battery cathodes. Science 376, 517–521 (2022).

Article  CAS  Google Scholar 

Jang, D. H. & Oh, S. M. Electrolyte effects on spinel dissolution and cathodic capacity losses in 4 V Li/Li_xMn₂O₄ rechargeable cells. J. Electrochem. Soc. 144, 3342 (1997).

Article  CAS  Google Scholar 

Sarapuu, A., Hussain, S., Kasikov, A., Pollet, B. G. & Tammeveski, K. Electroreduction of oxygen on Nafion®-coated thin platinum films in acid media. J. Electroanal. Chem. 848, 113292 (2019).

Article  CAS  Google Scholar 

Yang, C. et al. A novel approach to fabricate membrane electrode assembly by directly coating the Nafion ionomer on catalyst layers for proton-exchange membrane fuel cells. ACS Sustain. Chem. Eng. 8, 9803–9812 (2020).

Article  CAS  Google Scholar 

Sharma, P. P. & Kim, D. A facile and sustainable enhancement of anti-oxidation stability of Nafion membrane. Membranes 12, 521 (2022).

Article  CAS  Google Scholar